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Ikeda, Kazutaka*; Sashida, Sho*; Otomo, Toshiya*; Oshita, Hidetoshi*; Honda, Takashi*; Hawai, Takafumi*; Saito, Hiraku*; Ito, Shinichi*; Yokoo, Tetsuya*; Sakaki, Koji*; et al.
International Journal of Hydrogen Energy, 51(Part A), p.79 - 87, 2024/01
Times Cited Count：0 Percentile：0.01(Chemistry, Physical)Tang, J.*; Yamamoto, Susumu*; Koitaya, Takanori*; Yoshigoe, Akitaka; Tokunaga, Takuma*; Mukai, Kozo*; Matsuda, Iwao*; Yoshinobu, Jun*
Applied Surface Science, 480, p.419 - 426, 2019/06
Times Cited Count：10 Percentile：49.16(Chemistry, Physical)Mass transports during hydrogen adsorption and absorption processes of PdCu alloys that has advantages of higher hydrogen diffusivity and economically lower-cost than the other Pd-alloys were studied. The research was made with a comparison of the well-known ordered phase of the bcc structure (the B2 phase) and a mixed phase of the fcc and B2 structures. 
ultrahigh vacuum X-ray photoelectron spectroscopy and ambient pressure X-ray photoelectron spectroscopy using synchrotron radiation were carried out to trace the chemical states of the Pd and Cu atoms as a function of temperatures. It is elucidated that the initial adsorption and absorption processes were similar in the two phases, but a hydrogen diffusion rate to the bulk was higher in the ordered phase than in the mixed one. We found the dynamics of the Pd and Cu atoms during the hydrogen adsorption/absorption processes largely depend on temperature. In the hydrogen atmosphere, the Pd atoms segregate at the surface below 373 K and Cu atoms segregate at the surface above 373 K. The present results agree well with the previous theoretical calculations and, thus, provide appropriate inputs toward developments of the hydrogen permeation materials.
Abe, Hiroshi; Shimomura, Takuya; Tokuhira, Shinnosuke*; Shimada, Yukihiro*; Takenaka, Yusuke*; Furuyama, Yuta*; Nishimura, Akihiko; Uchida, Hirohisa*; Daido, Hiroyuki; Oshima, Takeshi
Proceedings of 7th International Congress on Laser Advanced Materials Processing (LAMP 2015) (Internet), 4 Pages, 2015/08
A short pulse laser (the nanosecond and femtosecond) was applied to hydrogen absorbing alloys surface layer, and a surface modification experiment was put into effective to aim at improvement of hydrogen adsorption functionally. It was investigated about correlation between an initial hydrogen absorption reaction rate of hydrogen alloys and a laser irradiation in this research. The laser irradiation condition was done with pulse width 100 fsec and energy 0.2 - 3.4 mJ/pulse. It blazed down on hydrogen absorbing alloys (LaNi
Al
) and changed local order in the surface. As a result, the initial hydrogen absorption reaction rate was 1.5 - 3.0 times as fast as a irradiated sample, and the result and laser irradiated sample found out that a hydrogen absorption function improves. A laser irradiation can conclude to be effective in surface modification of the hydrogen storage materials.
Matsubayashi, Masahito
Hihakai Kensa No Saizensen (CD-ROM), 7 Pages, 2002/00
no abstracts in English
Sakaguchi, Hiroki*; Hatakeyama, Keisuke*; Satake, Yuichi*; Fujine, Shigenori*; Yoneda, Kenji*; Kanda, Keiji*; Matsubayashi, Masahito; Esaka, Takao*
Kashika Joho Gakkai-Shi, 20(suppl.1), p.373 - 374, 2000/07
no abstracts in English
Ishiyama, Shintaro; Eto, Motokuni
Material Chemistry 96: Proc. of Int. Symp. on Material Chemistry in Nuclear Environment, 0, p.595 - 607, 1996/00
no abstracts in English
JAERI-Review 95-003, 90 Pages, 1995/03
JAERI-Review-95-003.pdf:3.47MB
no abstracts in English
P-type structure*; *; Shimojo, Yutaka; Morii, Yukio; *
Journal of Alloys and Compounds, 231(1-2), p.755 - 759, 1995/00
Times Cited Count：14 Percentile：67.55(Chemistry, Physical)no abstracts in English
Ishiyama, Shintaro; ; Eto, Motokuni
Journal of Alloys and Compounds, 231, p.895 - 897, 1995/00
Times Cited Count：1 Percentile：22.97(Chemistry, Physical)no abstracts in English
Ishiyama, Shintaro; ; Eto, Motokuni
Proc., Int. Hydrogen and Clean Energy Symp. ; IHCE 95, p.337 - 340, 1995/00
no abstracts in English
Abe, Hiroshi; Tokuhira, Shinnosuke*; Shimomura, Takuya; Shimada, Yukihiro*; Takenaka, Yusuke*; Furuyama, Yuta*; Nishimura, Akihiko; Daido, Hiroyuki; Uchida, Hirohisa*; Oshima, Takeshi
no journal, ,
no abstracts in English
